ELECTROPHORETIC STUDY OF RHODIUM AND PALLADIUM CATALYSTS SUPPORTED BYGAMMA-AL2O3 AND SIO2

Authors
CARKOVIC I GULPPI M VALERO E ESCUDEY M GILLLAMBIAS FJ
Citation
I. Carkovic et al., ELECTROPHORETIC STUDY OF RHODIUM AND PALLADIUM CATALYSTS SUPPORTED BYGAMMA-AL2O3 AND SIO2, Boletin de la Sociedad Chilena de Quimica, 43(3), 1998, pp. 287-295
Citations number
19
Categorie Soggetti
Chemistry
Journal title
Boletin de la Sociedad Chilena de Quimica → ACNP
ISSN journal
03661644
Volume
43
Issue
3
Year of publication
1998
Pages
287 - 295
Database
ISI
SICI code
0366-1644(1998)43:3<287:ESORAP>2.0.ZU;2-E
Abstract
Rh//gamma-Al2O3, Rh/SiO2, Pd/ gamma-Al2O3 and Pd/SiO2 catalysts with a metal content lower than 2.5%, supported by the incipient wetness met hod, were studied by electrophoretic method. It has been proved that t he metal is preferentially located at the periphery of the particles o f the support. It was proved, moreover, that the highest interaction b etween these metals and these supports is observed in the Rh/gamma-Al2 O3 system, while the lowest is observed in the Pd/SiO2 series; the int eraction between Rh and gamma-Al2O3 is greater than between Rh and SiO 2.