MECHANISM AND KINETICS OF THE ACID-CATALYZED DEHYDRATION OF 1-PROPANOL AND 2-PROPANOL IN HOT COMPRESSED LIQUID WATER

Only propene and 1-propanol are observed as products of the acid-catal yzed dehydration of 2-propanol in compressed liquid water after 100 s or less at 320 degrees C. Likewise, only propene, 2-propanol, and trac es of n-propyl ether are observed as products of the acid-catalyzed de hydration of 1-propanol under the same conditions. Kinetic analyses of the experimental data indicate that propene is formed from 1-propanol by an acid-catalyzed E2 mechanism that involves only protonated 1-pro panol as an intermediate. Byproduct n-propyl ether is formed by an Ad( E)3 mechanism involving propene, 1-propanol, and acid. The formation o f propene from 2-propanol is kinetically consistent with both an acid- catalyzed E2 mechanism and an acid-catalyzed E1 mechanism (that involv es the bare i-propyl cation in addition to protonated 2-propanol as in termediates in the dehydration chemistry). Thus, our kinetic analysis does not enable us to discriminate between the two mechanisms for 2-pr opanol dehydration. On the other hand, results of the kinetic analysis point to the important role of the undetected product i-propyl ether in the formation of propene from both 2-propanol and 1-propanol. This ether (which is not stable in hot liquid water) is formed by an Ad(E)3 mechanism and decomposes via an uncatalyzed, unimolecular reaction. E xperimental studies of the reactions of n-propyl ether and i-propyl et her are consistent with model predictions.