Two-dimensional near-field Raman spectra and topographic images of the
polydiacetylene surface are measured simultaneously by using a near-f
ield Raman spectrometer, The spectra (located 100 nm apart) have diffe
rent spectral features. The peak intensity ratio of two C=C peaks at 1
520 and 1457 cm(-1) does not correlate with the topographic image and
shows differences in the subwavelength scale. These differences can be
interpreted as spatial differences in the number of successive bonds
on the polydiacetylene surface. In contrast, the near-field Raman inte
nsity of the C=C bond at 1457 cm(-1) correlates strongly with the topo
graphic image. This phenomenon can be interpreted as a change in the e
fficiency of collecting Raman scattering light.