MOLECULAR RECOGNITION IN THE PALLADIUM COMPLEX PROMOTED ASYMMETRIC-SYNTHESIS OF A KETO-ESTER HETEROFUNCTIONALIZED P-CHIRAL PHOSPHINE

Authors
LEUNG PH LANG HF WHITE AJP WILLIAMS DJ
Citation
Ph. Leung et al., MOLECULAR RECOGNITION IN THE PALLADIUM COMPLEX PROMOTED ASYMMETRIC-SYNTHESIS OF A KETO-ESTER HETEROFUNCTIONALIZED P-CHIRAL PHOSPHINE, Tetrahedron : asymmetry, 9(17), 1998, pp. 2961-2964
Citations number
8
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Tetrahedron : asymmetry → ACNP
ISSN journal
09574166
Volume
9
Issue
17
Year of publication
1998
Pages
2961 - 2964
Database
ISI
SICI code
0957-4166(1998)9:17<2961:MRITPC>2.0.ZU;2-T
Abstract
A chiral organopalladium complex promoted asymmetric Diels-Alder react ion between 1-phenyl-3,4-dimethyl-phosphole and methyl-trans-4-oxo-2-p entenoate gives the corresponding keto-carboxylate heterofunctionalize d P-chiral phosphine ligand in which the keto group is stereoselective ly located in the exo position of the phosphanorbornene skeleton. (C) 1998 Elsevier Science Ltd. All rights reserved.