SYNTHESIS AND RADICAL FRAGMENTATION OF CARBOHYDRATE ANOMERIC NITRATES- FORMATION OF CONVENIENT CHIRAL SYNTHETIC INTERMEDIATES

Authors
FRANCISCO CG LEON EI MORENO P SUAREZ E
Citation
Cg. Francisco et al., SYNTHESIS AND RADICAL FRAGMENTATION OF CARBOHYDRATE ANOMERIC NITRATES- FORMATION OF CONVENIENT CHIRAL SYNTHETIC INTERMEDIATES, Tetrahedron : asymmetry, 9(17), 1998, pp. 2975-2978
Citations number
40
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Tetrahedron : asymmetry → ACNP
ISSN journal
09574166
Volume
9
Issue
17
Year of publication
1998
Pages
2975 - 2978
Database
ISI
SICI code
0957-4166(1998)9:17<2975:SARFOC>2.0.ZU;2-R
Abstract
A new procedure for the C1-C2 fragmentation of cyclic carbohydrates, t hrough the formation of anomeric alkoxy radicals from the correspondin g nitrate esters, with (Bu3SnH)-Bu-n/azobisisobutyronitrile (AIBN), af fords acyclic alditols in good yields. (C) 1998 Elsevier Science Ltd. All rights reserved.