SYNTHESIS OF HAMINOL-A AND HAMINOL-B, POLYENIC ALARM PHEROMONES OF CEPHALASPIDEAN MOLLUSKS

Authors
ALVAREZ R DELERA AR
Citation
R. Alvarez et Ar. Delera, SYNTHESIS OF HAMINOL-A AND HAMINOL-B, POLYENIC ALARM PHEROMONES OF CEPHALASPIDEAN MOLLUSKS, Tetrahedron : asymmetry, 9(17), 1998, pp. 3065-3072
Citations number
37
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Tetrahedron : asymmetry → ACNP
ISSN journal
09574166
Volume
9
Issue
17
Year of publication
1998
Pages
3065 - 3072
Database
ISI
SICI code
0957-4166(1998)9:17<3065:SOHAHP>2.0.ZU;2-O
Abstract
Two stereocontrolled palladium-catalyzed cross-couplings of I-alkenyl boronic acids and aryl/alkenyl halides (the Suzuki-Miyaura reaction) a re the key steps in an enantioselective approach to the polyene fragme nt of haminols A and B, alarm pheromones isolated from Haminoea navicu la, a Cephalaspidean Opisthobranch mollusc. Chirality rested on the us e of (S)-propylene oxide as the starting material. (C) 1998 Elsevier S cience Ltd. All rights reserved.