Sak. Jeelani et S. Hartland, EFFECT OF SURFACE MOBILITY ON COLLISION OF SPHERICAL DROPS, Journal of colloid and interface science (Print), 206(1), 1998, pp. 83-93
The collision of two spherical liquid drops is considered which allows
the effect of coalescence on the formation and stability of dispersio
ns to be studied. An analytical solution is derived for the variation
in the hydrodynamic force with the approach velocity and the separatio
n thickness during the impact in terms of the drop diameter, allowing
for the effect of induced flow inside the drops. Setting this force eq
ual to the rate of change of momentum of the drops enables the variati
on with time in the separation between the drops to be obtained in ter
ms of the initial approach velocity, drop diameter, and viscosity rati
o. The analysis also yields the time variation in the force and approa
ch velocity. For a given impact velocity, the separation thickness dec
reases with time until a minimum value is reached, which decreases as
the impact velocity and the viscosity ratio of the continuous and disp
ersed phases increase. Previous authors have only obtained the variati
on in the approach velocity with the unknown variable force and separa
tion thickness during the impact and therefore could not obtain the va
riation in the separation thickness with time. Knowing this variation
enables the possibility of coalescence during impact to be investigate
d. Coalescence is influenced by the minimum separation thickness attai
ned at low impact velocities and by drop deformation and inertial drai
nage at high velocities. (C) 1998 Academic Press.