Jc. Austin et Re. Challis, THE EFFECTS OF FLOCCULATION ON THE PROPAGATION OF ULTRASOUND IN DILUTE KAOLIN SLURRIES, Journal of colloid and interface science (Print), 206(1), 1998, pp. 146-157
A broadband ultrasonic spectrometer has been used to measure ultrasoni
c attenuation and phase velocity dispersion as functions of frequency
in kaolin suspensions over a range of solid volume fractions from phi
= 0.01 to phi = 0.08 and over a pH range from 3 to 9. The Harker and T
emple theory was used to simulate ultrasound propagation in the suspen
sion, using measured slope viscosity, particle size, and size distribu
tion. Simulated results for ultrasonic attenuation and phase velocity
agree well with measured values. Both sets of results agree well and s
how that for volume fractions above phi similar to 0.05 attenuation an
d velocity dispersion increase for increasing flee size, whereas for v
olume fractions below phi similar to 0.05 attenuation and velocity dis
persion both decrease. It is proposed that the mechanism for this chan
ge in behavior around phi similar to 0.05 involves changes in flee den
sity and flee size distribution with phi and pH. (C) 1998 Academic Pre
ss.