MOLECULAR-STRUCTURE AND ABSOLUTE-CONFIGURATION OF YL)-ENDO-TRICYCLO[5.2.1.0(2,6)]DECA-4,8-DIEN-3-ONE

Authors
DEGELDER R SMITS JMM RAMESH NG BAKKEREN FJAD KLUNDER AJH
Citation
R. Degelder et al., MOLECULAR-STRUCTURE AND ABSOLUTE-CONFIGURATION OF YL)-ENDO-TRICYCLO[5.2.1.0(2,6)]DECA-4,8-DIEN-3-ONE, Journal of chemical crystallography, 28(6), 1998, pp. 493-495
Citations number
11
Categorie Soggetti
Crystallography,Spectroscopy
Journal title
Journal of chemical crystallography → ACNP
ISSN journal
10741542
Volume
28
Issue
6
Year of publication
1998
Pages
493 - 495
Database
ISI
SICI code
1074-1542(1998)28:6<493:MAAOY>2.0.ZU;2-O
Abstract
The crystal and molecular structure yl)-endo-tricyclo[5.2.1.0(2,6)]dec a-4,8-dien-3-one is described. Knowing the absolute configuration of t he prolinol moiety (S) the X-ray diffraction study established the abs olute configuration of the title compound. The structure was refined t o R-1 = 0.0322 for 1237 reflections (with I greater-than 2 sigma(I)). Crystal data: C15H19NO2, monoclinic, space group P2(1), a = 6.0757(4), b = 11.3473(5), c = 9.5114(7)Angstrom, beta = 104.686(6)degrees, V = 634.32(7) Angstrom(3), and Z = 2.