PREPARATION AND PROPERTIES OF POLYMERIC CONDUCTIVE NICKEL-COMPLEXES OF TETRATHIAFULVALENE TETRATHIOLATE LIGAND

Authors
TANG Y GAN XM TAN MY ZHENG XQ
Citation
Y. Tang et al., PREPARATION AND PROPERTIES OF POLYMERIC CONDUCTIVE NICKEL-COMPLEXES OF TETRATHIAFULVALENE TETRATHIOLATE LIGAND, Synthetic metals, 97(1), 1998, pp. 43-46
Citations number
19
Categorie Soggetti
Physics, Condensed Matter","Material Science","Polymer Sciences
Journal title
Synthetic metals → ACNP
ISSN journal
03796779
Volume
97
Issue
1
Year of publication
1998
Pages
43 - 46
Database
ISI
SICI code
0379-6779(1998)97:1<43:PAPOPC>2.0.ZU;2-V
Abstract
The preparation and properties of two series of polymers based on nick el complexes of the tetrathiafulvalene tetrathiolate (ttftt) of stoich iometry [ (Ni-ttftt)M-x](n) (M = Mn, Co, Ni, Cu, Hg; x = 0.9, 1.1, 1.0 , 1.0, 0.8) and [ (Ni-ttftt) Ln(y)](n) (Ln = La, Sm, Eu; y = 0.7; Ln = Gd, TD, Er; y= 0.6) are described. The insoluble amorphous polymer co mplexes have been characterized by elemental analysis, IR spectra, TG- DTA techniques, X-ray photoelectron spectroscopy and conductivity meas urements. As compacted pellets, these complexes behave as semiconducto rs at 25 degrees C. (C) 1998 Elsevier Science S.A. All rights reserved .