S. Sato et al., STUDY ON THE APPLICATION OF THE -2-METHYL-1,3-BENZODIOXOLE-4-CARBOXYLIC-ACID-BASED ONLINE HPLC-EXCITON CD ANALYSIS TO ACYCLIC 1,3-DIOLS, Bioscience, biotechnology, and biochemistry, 62(9), 1998, pp. 1822-1825
The application of the on-line HPLC-exciton Co analysis with (S)-TBMB-
carboxylic acid that simultaneously determined the enantiomeric compos
ition and absolute configuration of vicinal diols, diamines and amino
alcohols to 1,3-diols was studied. All optical isomers of di-O-(S)-TBM
B-carbonyl-1,3-butanediols and 2,4-pentanediols were separated and the
ir absolute configurations were determined without reference samples o
n line by HPLC.