Sh. Moon et S. Lee, AN EFFICIENT CONVERSION OF CHIRAL ALPHA-AMINO-ACIDS TO ENANTIOMERICALLY PURE 3-AMINO CYCLIC AMINES, Synthetic communications, 28(21), 1998, pp. 3919-3926
Enantiomerically pure 3-amino cyclic amines such as 3-amino pyrrolidin
e, 3-amino piperidine, and 2.,3,4,5,6,7-hexahydro-1H-azepine have been
synthesized in high yields from the optically active natural a-amino
acids such as L-aspartic acid, L-glutamic acid, L-2-aminoadipic acid,
and their enantiomers.