LINE BROADENING IN THE FUNDAMENTAL-BAND OF CO IN CO-HE AND CO-AR MIXTURES

Citation
Pm. Sinclair et al., LINE BROADENING IN THE FUNDAMENTAL-BAND OF CO IN CO-HE AND CO-AR MIXTURES, Journal of molecular spectroscopy (Print), 191(2), 1998, pp. 258-264
Citations number
32
Categorie Soggetti
Spectroscopy,"Physics, Atomic, Molecular & Chemical
ISSN journal
00222852
Volume
191
Issue
2
Year of publication
1998
Pages
258 - 264
Database
ISI
SICI code
0022-2852(1998)191:2<258:LBITFO>2.0.ZU;2-6
Abstract
We present accurate broadening coefficients for many lines of the fund amental band of CO highly diluted in He and Ar at 301.5 K. It is shown that a soft collision model gives a reasonable fit to the data at pre ssures up to 1 atm. A distinction is drawn between the accuracy with w hich fitting parameters may be determined and the accuracy with which a spectral profile fits experimental data. Differences between a model profile and the experimental profile are quantified, and the underlyi ng physics omitted from the spectral model is briefly discussed. (C) 1 998 Academic Press.