THE CORRELATION BETWEEN MOLECULAR AND CHE MICAL-DYNAMICS FOR ELEMENTARY RADICAL REACTIONS IN VISCOSE MEDIA

Authors
RAKHIMOV RR PROKOFEV AI LEBEDEV YS
Citation
Rr. Rakhimov et al., THE CORRELATION BETWEEN MOLECULAR AND CHE MICAL-DYNAMICS FOR ELEMENTARY RADICAL REACTIONS IN VISCOSE MEDIA, Uspehi himii, 62(6), 1993, pp. 547-565
Citations number
58
Categorie Soggetti
Chemistry
Journal title
Uspehi himii → ACNP
ISSN journal
00421308
Volume
62
Issue
6
Year of publication
1993
Pages
547 - 565
Database
ISI
SICI code
0042-1308(1993)62:6<547:TCBMAC>2.0.ZU;2-G
Abstract
The analysis experimental data of the effect of viscosity on free radi cal elementar chemical reactions kinetics was made. The dynamics effec ts in EPR spectroscopy were used for parallel investigation of molecul ar and chemical dynamics. Intramolecular reactions of free radicals an d spin exchange in biradicals are considered. It is shown that these i ntramolecular processes are controlled by molecular dynamics of the ca ge. Bibliography - 58 references.