SOME ASPECTS OF POLYMER PYROLYSIS

Citation
Ge. Zaikov et Rm. Aseeva, SOME ASPECTS OF POLYMER PYROLYSIS, Die Makromolekulare Chemie. Macromolecular symposia, 74, 1993, pp. 21-33
Citations number
7
Categorie Soggetti
Polymer Sciences
ISSN journal
02580322
Volume
74
Year of publication
1993
Pages
21 - 33
Database
ISI
SICI code
0258-0322(1993)74:<21:SAOPP>2.0.ZU;2-M
Abstract
Pyrolysis is the important stage of polymer combustion. This process d epends on molecular and submolecular structure of polymer as well as c onditions of heat affect. It may be realized through the formation of nonvolatile carbonized product. The basic conception of the present wo rk consists in the transformation of macromolecules into carbonized st ructure which realises by means of formation of the thermodynamically- advantageous intermediate compounds with a system of pi-conjugated uns aturated carbon bonds (acyclic or aromatic nature) and by their follow ing conversion into condensed aromatic structures. It has been examine d the correlation between the structure and properties of carbonized p roducts and the flammability of polymers.