1,2-BIS(1',3'-DIMETHYLIMIDAZOLIN-2'-IMINATO)ETHANE - A NOVEL CHELATING LIGAND

Authors
KUHN N GRATHWOHL M STEIMANN M HENKEL G
Citation
N. Kuhn et al., 1,2-BIS(1',3'-DIMETHYLIMIDAZOLIN-2'-IMINATO)ETHANE - A NOVEL CHELATING LIGAND, Zeitschrift fur Naturforschung. B, A journal of chemical sciences, 53(9), 1998, pp. 997-1003
Citations number
28
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur Naturforschung. B, A journal of chemical sciences → ACNP
ISSN journal
09320776
Volume
53
Issue
9
Year of publication
1998
Pages
997 - 1003
Database
ISI
SICI code
0932-0776(1998)53:9<997:1-ANC>2.0.ZU;2-I
Abstract
The reaction of 2-imino-1,3-dimethylimidazoline (10, ImNH) with X-CH2C H2-X (11, X = p-CH3C6H4SO3) gives the diimine adduct ImN-CH2CH2-NIm . 2 HX (12) from which the diimine ImN-CH2CH2-NIm (13) is obtained on tr eatment with KH. 13 reacts with (C6H5CN)(2)PdCl2 (15) to give the chel ate complex (ImN-CH2CH2-NIm)PdCl2 (16). The X-ray structures of 12 and 16 are reported.