A series of novel esters of 4-carboxyphthalimides has been prepared. D
ifferential scanning calorimetry and polarizing optical microscopy stu
dies reveal that N-substituted 4-cholesteryloxycarboxyphthalimides exh
ibit a chiral nematic (cholesteric) phase in the range 120-205-degrees
-C. Unexpectedly, esters containing well-known mesogenic groups such a
s 4-cyano- or 4-methoxy-phenyl do not form liquid crystal phases.