SYNTHESIS AND PROPERTIES OF SUPERPHANES WITH CYCLOPENTADIENONE UNITS

Authors
ROERS R ROMINGER F BRAUNWEILER C GLEITER R
Citation
R. Roers et al., SYNTHESIS AND PROPERTIES OF SUPERPHANES WITH CYCLOPENTADIENONE UNITS, Tetrahedron letters, 39(43), 1998, pp. 7831-7834
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
39
Issue
43
Year of publication
1998
Pages
7831 - 7834
Database
ISI
SICI code
0040-4039(1998)39:43<7831:SAPOSW>2.0.ZU;2-Q
Abstract
A metal supported [2+2+1]cycloaddition of two cyclic alkynes and one C O group is the key step for the preparation of the first superphanes ( 1, 2) with a metal-capped cyclopentadienone ring. Cyclic voltammetry r eveals a strong interaction between the two pi-systems in 2. (C) 1998 Elsevier Science Ltd. All rights reserved.