SHORT SYNTHESIS OF THE BICYCLIC CORE OF THE ZARAGOZIC ACIDS

Citation
P. Fraisse et al., SHORT SYNTHESIS OF THE BICYCLIC CORE OF THE ZARAGOZIC ACIDS, Tetrahedron letters, 39(43), 1998, pp. 7853-7856
Citations number
27
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404039
Volume
39
Issue
43
Year of publication
1998
Pages
7853 - 7856
Database
ISI
SICI code
0040-4039(1998)39:43<7853:SSOTBC>2.0.ZU;2-R
Abstract
A synthesis of the highly functionalized bicyclic core of the zaragozi c acids is described, in which the key step involves the construction of the C4 quaternary carbon center by a CeCl3-promoted aldol reaction between the alpha-D-xylofuranuronic acid derivative 2 and D-(R)-glycer aldehyde acetonide. (C) 1998 Published by Elsevier Science Ltd. All ri ghts reserved.