CATALYSIS BY TOPOLOGICALLY ANCHORED METAL-COMPLEXES - LIQUID-PHASE HYDROXYLATION OF BENZENE BY H2O2 IN THE PRESENCE OF ZEOLITE-SUPPORTED FE(II) PHTHALOCYANINE

Authors
ZEFIROV NS ZAKHAROV AN
Citation
Ns. Zefirov et An. Zakharov, CATALYSIS BY TOPOLOGICALLY ANCHORED METAL-COMPLEXES - LIQUID-PHASE HYDROXYLATION OF BENZENE BY H2O2 IN THE PRESENCE OF ZEOLITE-SUPPORTED FE(II) PHTHALOCYANINE, Canadian journal of chemistry, 76(6), 1998, pp. 955-959
Citations number
12
Categorie Soggetti
Chemistry
Journal title
Canadian journal of chemistry → ACNP
ISSN journal
00084042
Volume
76
Issue
6
Year of publication
1998
Pages
955 - 959
Database
ISI
SICI code
0008-4042(1998)76:6<955:CBTAM->2.0.ZU;2-S
Abstract
Fe(LI) phthalocyanine topologically anchored on NaA zeolite has been p repared. The catalytic activity of zeolite-supported Fe(II) phthalocya nine has been studied in the liquid-phase hydroxylation of benzene by H2O2. The main product of the reaction at room temperature is phenol. By refluxing, the reaction proceeds to give the products of subsequent oxidation, i.e., hydroquinone and p-benzoquinone, in low yields.