SYNTHESIS OF LA-2(MOO4)(3) - ELECTROCATALYTIC ACTIVITY FOR THE OXYGENEVOLUTION IN ALKALINE MEDIA

Citation
Gp. Gonzalezrojas et al., SYNTHESIS OF LA-2(MOO4)(3) - ELECTROCATALYTIC ACTIVITY FOR THE OXYGENEVOLUTION IN ALKALINE MEDIA, International journal of hydrogen energy, 23(11), 1998, pp. 999-1003
Citations number
10
Categorie Soggetti
Energy & Fuels","Physics, Atomic, Molecular & Chemical","Environmental Sciences
ISSN journal
03603199
Volume
23
Issue
11
Year of publication
1998
Pages
999 - 1003
Database
ISI
SICI code
0360-3199(1998)23:11<999:SOL-EA>2.0.ZU;2-T
Abstract
La-Mo oxides were synthesised by heating the powder, obtained from the reaction of lanthanum nitrate with molybdenum carbonyl in organic med ia, at 573 K for 2 h. The structure, morphology and chemical compositi on were determined by oxygen determination, atomic absorption spectrom etry, X-ray diffraction and scanning electron microscopy. The results showed an amorphous structure. After heating the compound in vacuum, w e obtained the X-ray diffraction pattern of La-2(MoO4)(3). The electro chemical behaviour of the La-Mo oxides was determined in KOH 0.5 M. In the range 700-1000 mV vs Hg/HgO/KOH 0.5 M electrode, the results show ed a very good performance for the oxygen evolution reaction. (C) 1998 International Association for Hydrogen Energy.