OSCILLATORY CONDUCTANCE OF CARBON-ATOM WIRES

The conductance of carbon-atom chains is found from first-principles c alculations to vary in an oscillatory manner as the number of carbon a toms is increased, with odd-numbered chains having a lower resistance than even-numbered chains. This finding is explained in terms of the e lectronic structure of the free chains and its modification by interac tion with the metal electrodes: the critical factor is the density of states at the Fermi level of the combined electrode-atomic-wire system . Stronger electrode-atomic-wire coupling, i.e., shorter metal-carbon distance, does not necessarily imply a higher conductance.