A FACILE SYNTHESIS OF RHODIUM(III) PORPHYRIN-SILYLS

Authors
TSE AKS WU BM MAK TCW CHAN KS
Citation
Aks. Tse et al., A FACILE SYNTHESIS OF RHODIUM(III) PORPHYRIN-SILYLS, Journal of organometallic chemistry, 568(1-2), 1998, pp. 257-261
Citations number
29
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
568
Issue
1-2
Year of publication
1998
Pages
257 - 261
Database
ISI
SICI code
0022-328X(1998)568:1-2<257:AFSORP>2.0.ZU;2-S
Abstract
Rhodium(III) porphyrin-silyls [Me3SiRhT(p-X)PP (X = H, Me)] were synth esized from the reactions of the rhodium(I) porphyrin anions, generate d from the reduction of the rhodium(III) porphyrin chlorides with the sodium amalgam in toluene, with degassed Me3SiCl at room temperature. A single crystal structure of traphenylporphyrinato)(trimethylsilyl)rh odium(III) (1) showed that the Rh-si bond length is equal to 2.305 Ang strom. (C) 1998 Elsevier Science S.A. All rights reserved.