We present the observation of VUV transitions between doubly excited s
tates of Ne7+. Spectra were selectively produced by single electron ca
pture in a cesium vapor by Ne8+ ions prepared in the metastable state
1s2s S-3 by a previous collision of a Ne9+ beam with a gas target. The
observed lines were assigned to 1s2l2l' --> 1s2lnl '' and 1s2l3d -->
1s2lnf electric dipole transitions. Furthermore, the forbidden electri
c quadrupole transition 1s2s2p P-4(o)-1s2p3d F-4(o) has been identifie
d at 78.71 Angstrom.