G. Diaz et al., CARBON NANOTUBES PREPARED BY CATALYTIC DECOMPOSITION OF BENZENE OVER SILICA-SUPPORTED COBALT CATALYSTS, Fullerene science and technology, 6(5), 1998, pp. 853-866
Carbon nanostructures were prepared by catalytic decomposition of benz
ene on Co/SiO2 catalysts at 873 K. As a function of particle size and
reactive mixture, carbon filaments and nanotubes were obtained and var
ious shapes observed such as straight, curved and helically-coiled nan
otubes. Particularly, it was shown that the helically-coiled nanotubes
do not present an ordered atomic structure as it was predicted theore
tically. However, the active catalytic particle as well as the reactiv
e environment may play an important role in the growth of such nanostr
uctures.