HIGHLY SELECTIVE HYDROCARBOXYLATION OF STYRENE WITH OXALIC-ACID OR WATER USING PALLADIUM ORTHO-AMINO ARENETHIOLATES WITH INTRAMOLECULAR COORDINATING NITROGEN LEWIS-BASES
D. Kruis et al., HIGHLY SELECTIVE HYDROCARBOXYLATION OF STYRENE WITH OXALIC-ACID OR WATER USING PALLADIUM ORTHO-AMINO ARENETHIOLATES WITH INTRAMOLECULAR COORDINATING NITROGEN LEWIS-BASES, INORGANIC CHEMISTRY COMMUNICATIONS, 1(8), 1998, pp. 295-298
Under mild conditions and in the presence of a catalytic amount of an
S,N-chelated palladium ortho-amino arenethiolate complex, styrene reac
ts with carbon monoxide and oxalic acid or water to selectively give 2
-phenylpropanoic acid in high yield. (C) 1998 Elsevier Science S.A. Al
l rights reserved.