ATOM ADDITION AND INSERTION REACTIONS OF (MECP)(2)TA(H)CO WITH SULFUR, TELLURIUM, CARBONYL SULFIDE AND CARBON-DISULFIDE

Authors
WINKLER U KHAN MA NICHOLAS KM
Citation
U. Winkler et al., ATOM ADDITION AND INSERTION REACTIONS OF (MECP)(2)TA(H)CO WITH SULFUR, TELLURIUM, CARBONYL SULFIDE AND CARBON-DISULFIDE, INORGANIC CHEMISTRY COMMUNICATIONS, 1(8), 1998, pp. 317-319
Citations number
14
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
INORGANIC CHEMISTRY COMMUNICATIONS → ACNP
ISSN journal
13877003
Volume
1
Issue
8
Year of publication
1998
Pages
317 - 319
Database
ISI
SICI code
1387-7003(1998)1:8<317:AAAIRO>2.0.ZU;2-1
Abstract
The reaction of (MeCp)(2)Ta(H)CO (Ib) with S-8 produces (MeCp)(2)Ta(SH )CO (2) and one or more transient eta(2)-COS complexes. Tellurium reac ts with Ib to afford unstable (MeCp)(2)Ta(TeH) CO (4) and putative (Me Cp)(2)Ta(TeH) (eta(2)-COTe) (5). Photoreaction of 1b with COS produces (MeCp)(2)Ta(mu(2)-S) (mu(2)-S)Ta(MeCp)(2) (6) which has been characte rized by X-ray diffraction. The reaction of Ib with cs, gives (MeCp)(2 )Ta(CO)(eta(1)-S2CH) (8). (C) 1998 Published by Elsevier Science S.A. All rights reserved.