(MU-OXO OR HYDROXO)BIS(MU-CARBOXYLATO)DIRUTHENIUM(III) COMPLEXES WITHTRIS(1-PYRAZOLYL)BORATE FACE-CAPPING LIGAND, AFFORDING VERSATILE OXIDATION-STATES VIA A PROTONATION DEPROTONATION COUPLE/

Authors
TANASE T TAKESHITA N YANO S KINOSHITA I ICHIMURA A
Citation
T. Tanase et al., (MU-OXO OR HYDROXO)BIS(MU-CARBOXYLATO)DIRUTHENIUM(III) COMPLEXES WITHTRIS(1-PYRAZOLYL)BORATE FACE-CAPPING LIGAND, AFFORDING VERSATILE OXIDATION-STATES VIA A PROTONATION DEPROTONATION COUPLE/, New journal of chemistry, 22(9), 1998, pp. 927-929
Citations number
16
Categorie Soggetti
Chemistry
Journal title
New journal of chemistry → ACNP
ISSN journal
11440546
Volume
22
Issue
9
Year of publication
1998
Pages
927 - 929
Database
ISI
SICI code
1144-0546(1998)22:9<927:(OHCW>2.0.ZU;2-P
Abstract
(mu-Oxo or mu-hydroxo)bis(mu-acetate)diruthenium(III) complexes with t ris(1-pyrazolyl)borate, [Ru-2(III)(mu-O)(mu-CH3COO)(2)(HBpz(3))(2)] (1 ) and [Ru-2(III)(mu-OH)(mu-CH3COO)(2)(HBpz(3))(2)](PF6) (2), have been prepared and characterized by X-ray crystallography, and showed a wid e range of redox processes, Ru-2(II) <-> (RuRuIII)-Ru-II<->Ru-2(III) < --> (RuRuIV)-Ru-III <-> Ru-2(IV) coupled with protonation/deprotonatio n at the bridged monoatom.