AN INVESTIGATION OF THE ZERO-FIELD SPLITTING AND OPTICAL-SPECTRA IN AGX-NI2+ (X=CL,BR)

Authors
CHEN JJ DU ML
Citation
Jj. Chen et Ml. Du, AN INVESTIGATION OF THE ZERO-FIELD SPLITTING AND OPTICAL-SPECTRA IN AGX-NI2+ (X=CL,BR), Physica. B, Condensed matter, 215(2-3), 1995, pp. 260-262
Citations number
10
Categorie Soggetti
Physics, Condensed Matter
Journal title
Physica. B, Condensed matter → ACNP
ISSN journal
09214526
Volume
215
Issue
2-3
Year of publication
1995
Pages
260 - 262
Database
ISI
SICI code
0921-4526(1995)215:2-3<260:AIOTZS>2.0.ZU;2-C
Abstract
The optical spectra of AgX:Ni2+ (X = Cl, Br) in the O-h system, and th e ZFS parameter D in the axial system have been calculated by means of the mu K alpha model of the Ni2+-6X(-) (X = F, Cl, Br, I) cluster. Th e calculation shows that the band distance in AgX:Ni2+ has been reduce d isotropically and the axial system should be dependent on the Ni2+-v acancy along the z-axis. The results agree well with experimental find ings.