Ds. Shin et al., EFFECTS OF MORPHOLOGICAL-CHANGES OF PT SRBI2TA2O9 INTERFACE ON THE ELECTRICAL-PROPERTIES OF FERROELECTRIC CAPACITOR/, JPN J A P 1, 37(9B), 1998, pp. 5189-5191
Morphological changes have been observed at the interface of Pt/SrBi2T
a2O9 (SBT) before and after annealing at 600 and 800 degrees C after d
epositing Pt top electrode. We have investigated leakage currents, bre
akdown voltages, and capacitances of Pt/SBT/Pt/SiO2/Si capacitor and P
t/SBT/CeO2/Si gate structure. As a result, the leakage cut-rent densit
y and capacitance are reduced from 10(-7) to 10(-8) A/cm(2) and 1.3 x
10(-10) to 8.5 x 10(-)11 F/cm(2), respectively; and breakdown voltage
increases from 5 to 14 V after post-annealing. The reduced leakage cur
rent density and increased breakdown voltage in the annealed samples a
re due to the smooth morphology of the interface of Pt/SBT. In the as-
deposited Pt top electrode on SET films, high electric field intensity
is generated due to small are of the valleys filled with fine Pt grai
ns, resulting in higher leakage current density than the post-annealed
Pt top electrode. Although the total gate capacitance of the post-ann
ealed sample is reduced by the non-contact area due to voids at the in
terface of Pt/SBT, memory window of the ferroelectric gate is not infl
uenced by such voids.