POLYURETHANE DENDRIMERS VIA CURTIUS REACTION

Authors
TAYLOR RT PUAPAIBOON U
Citation
Rt. Taylor et U. Puapaiboon, POLYURETHANE DENDRIMERS VIA CURTIUS REACTION, Tetrahedron letters, 39(44), 1998, pp. 8005-8008
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
39
Issue
44
Year of publication
1998
Pages
8005 - 8008
Database
ISI
SICI code
0040-4039(1998)39:44<8005:PDVCR>2.0.ZU;2-Y
Abstract
Reaction of 5-(t-butyldiphenylsiloxy)propyloxyisophthalic with dodecan ol and diphenylphosphoryl azide (DPPA) affords the diurethane via Curt ius reaction. Removal of the silyl group affords an alcohol which unde rgoes similar reaction with,the isophthalic acid. Iteration of the pro cess affords dendritic wedges through generation four, which can be at tached to 1,3,5-benzenetricarboxylic acid in the same fashion. Materia ls are characterized by NMR and MALDI-TOF mass spectrometry. (C) 1998 Elsevier Science Ltd. All rights reserved.