PALLADIUM-CATALYZED ACYLATION REACTIONS OF ALPHA,BETA-UNSATURATED KETONES WITH ACYLZIRCONOCENE CHLORIDE - REMARKABLE CONTROL OF 1,2-SELECTIVITY AND 1,4-SELECTIVITY BY THE CATALYST

Authors
HANZAWA Y TABUCHI N TAGUCHI T
Citation
Y. Hanzawa et al., PALLADIUM-CATALYZED ACYLATION REACTIONS OF ALPHA,BETA-UNSATURATED KETONES WITH ACYLZIRCONOCENE CHLORIDE - REMARKABLE CONTROL OF 1,2-SELECTIVITY AND 1,4-SELECTIVITY BY THE CATALYST, Tetrahedron letters, 39(44), 1998, pp. 8141-8144
Citations number
3
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
39
Issue
44
Year of publication
1998
Pages
8141 - 8144
Database
ISI
SICI code
0040-4039(1998)39:44<8141:PAROAK>2.0.ZU;2-5
Abstract
Palladium-catalyzed reactions of alpha,beta-unsaturated ketones with a cylzirconocene chloride showed not only an efficient acyl transfer to alpha,beta-unsaturated ketones but also a remarkable regiochemical con trol by selecting PdCl2(Ph-3)(2) or Pd(OAc)(2). (C) 1998 Elsevier Scie nce Ltd. All rights reserved.