We report on photoluminescence and Raman scattering performed at low t
emperature (T = 10 K) on GaAs/Al0.3Ga0.7As quantum-well wires with eff
ective wire widths of L = 100.0 and 10.9 nm prepared by molecular beam
epitaxial growth followed by holographic patterning, reactive ion etc
hing, and anodic thinning. We find evidence for the existence of longi
tudinal optical phonon modes confined to the GaAs quantum wire. The ob
served frequency at omega(L10) = 285.6 cm(-1) for L = 11.0 nm is in go
od agreement with that calculated on the basis of the dispersive diele
ctric continuum theory of Enderlein dagger as applied to the GaAs/Al0.
3Ga0.7As system. Our results indicate the high crystalline quality of
the quantum-well wires fabricated using these techniques. (C) 1998 Aca
demic Press.