PREPARATION, STRUCTURE AND OPTICAL-PROPERTIES OF [CH3SC(=NH2)NH2](3)PBI5, [CH3SC(=NH2)NH2](4)PB2BR8 AND H3SC(=NH2)NH2](3)PBCL5-CENTER-DOT-CH3SC(=NH2)NH2CL

Authors
MOUSDIS GA GIONIS V PAPAVASSILIOU GC RAPTOPOULOU CP TERZIS A
Citation
Ga. Mousdis et al., PREPARATION, STRUCTURE AND OPTICAL-PROPERTIES OF [CH3SC(=NH2)NH2](3)PBI5, [CH3SC(=NH2)NH2](4)PB2BR8 AND H3SC(=NH2)NH2](3)PBCL5-CENTER-DOT-CH3SC(=NH2)NH2CL, Journal of materials chemistry (Print), 8(10), 1998, pp. 2259-2262
Citations number
22
Categorie Soggetti
Chemistry Physical","Material Science
Journal title
Journal of materials chemistry (Print) → ACNP
ISSN journal
09599428
Volume
8
Issue
10
Year of publication
1998
Pages
2259 - 2262
Database
ISI
SICI code
0959-9428(1998)8:10<2259:PSAOO[>2.0.ZU;2-F
Abstract
The preparation, crystal structures and optical absorption spectra of [CH3SC (= NH2)NH2](3)PbI5 1, [CH3SC (=NH2)NH2](4)Pb2Br8 2 and [CH3SC(= NH2)NH2](3)PbCl5. CH3SC (=NH2)NH2Cl 3 are reported. Compounds 1 and 3 consist of deformed PbX6, octahedra, which share opposite corners to f orm quasi-zero-dimensional or one-dimensional infinite chains along th e a-axis. Compound 2 consists of Pb2Br9 units which-are connected with two neighbouring units by non-opposite Br atoms; in this way, infinit e zigzag chains are formed. A blue shift of the excitonic absorption b ands, in comparison to those of systems with higher dimensionality, is observed.