STRUCTURE OF BIS[(S)-PROLINAMIDATO]-COPPER(II) DIHYDRATE

Authors
FAVA GG FERRARI MB PELOSI G DEMUNARI E CORRADINI R MARCHELLI R DOSSENA A
Citation
Gg. Fava et al., STRUCTURE OF BIS[(S)-PROLINAMIDATO]-COPPER(II) DIHYDRATE, Acta crystallographica. Section C, Crystal structure communications, 49, 1993, pp. 1449-1452
Citations number
21
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
49
Year of publication
1993
Part
8
Pages
1449 - 1452
Database
ISI
SICI code
0108-2701(1993)49:<1449:SOBD>2.0.ZU;2-#
Abstract
Crystals of bis[(S)-prolinamidato]copper(II) have been prepared and th eir structure determined by X-ray crystallography. The Cu coordination is tetrahedrally distorted square planar. An O atom of a molecule rel ated by a twofold screw axis interacts weakly with Cu(II), serving as a bridging element to form a polymeric structure. A new chiral centre of (S) configuration is produced at the amino N atom on coordination t o Cu(II).