STRUCTURE OF OHEXYL-PHOSPHINO)ETHANE]GOLD(I))BIS(DICYANOAURATE)

Authors
MCCLESKEY TM HENLING LM FLANAGAN KA GRAY HB
Citation
Tm. Mccleskey et al., STRUCTURE OF OHEXYL-PHOSPHINO)ETHANE]GOLD(I))BIS(DICYANOAURATE), Acta crystallographica. Section C, Crystal structure communications, 49, 1993, pp. 1467-1469
Citations number
10
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
49
Year of publication
1993
Part
8
Pages
1467 - 1469
Database
ISI
SICI code
0108-2701(1993)49:<1467:SOO>2.0.ZU;2-V
Abstract
The compound H2CH2P(C6H11)2})2-{mu-(C6H11)2PCH2CH2P(C6H11)2}]2+ [Au(CN )2]2(2-) luminesces strongly (lambda(max) = 508 nm) in acetonitrile at room temperature. Both gold(I) atoms are in trigonal planar environme nts, bound to one chelating bis(dicyclohexylphosphino)ethane (dcpe), a nd linked to one another by one bridging dcpe. The bridging unit is st retched with an Au...Au distance of 7.0501 angstrom; clearly no Au-Au interaction is present.