CHLORO(TRIMESITYLPHOSPHINE)GOLD(I)

Authors
ALYEA EC FERGUSON G GALLAGHER JF MALITO J
Citation
Ec. Alyea et al., CHLORO(TRIMESITYLPHOSPHINE)GOLD(I), Acta crystallographica. Section C, Crystal structure communications, 49, 1993, pp. 1473-1476
Citations number
16
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
49
Year of publication
1993
Part
8
Pages
1473 - 1476
Database
ISI
SICI code
0108-2701(1993)49:<1473:C>2.0.ZU;2-1
Abstract
Chloro(trimesitylphosphine)gold(I), [AuCl(C9H11)P3], has approximate t hreefold symmetry in the solid state [dihedral angles between the mesi tyl ring planes and the relevant Au-P-C planes are 47.0 (1), 48.0 (1) and 48.5 (1)-degrees]. The Au atom has a linear coordination geometry with Au-Cl and Au-P bond lengths of 2.2716 (19) and 2.2634 (15) angstr om, respectively, and a P-Au-Cl bond angle of 178.01 (8)-degrees. The C(ar)-C(ar) bond lengths are in the range 1.360 (10) to 1.424 (8) angs trom, while the range of C(ar)-C(sp)3 distances lies between 1.499 (10 ) and 1.529 (9) angstrom.