FUNCTIONALIZED HYDROCARBONS WITH CONDENSED RING SKELETONS .13. A SUBSTITUTED 1-METHYLTRICYCLO[7.4.0.02,6]-TRIDEC-7-ENE

Authors
MICHEL AG DROUIN M
Citation
Ag. Michel et M. Drouin, FUNCTIONALIZED HYDROCARBONS WITH CONDENSED RING SKELETONS .13. A SUBSTITUTED 1-METHYLTRICYCLO[7.4.0.02,6]-TRIDEC-7-ENE, Acta crystallographica. Section C, Crystal structure communications, 49, 1993, pp. 1500-1502
Citations number
14
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
49
Year of publication
1993
Part
8
Pages
1500 - 1502
Database
ISI
SICI code
0108-2701(1993)49:<1500:FHWCRS>2.0.ZU;2-Z
Abstract
The structure of .0.0(2,6)]tridec-7-ene-10,11-diol-4,2-carbolactone mo nohydrate (methyl ano-3,4,4a,6a,-7,8,9,10,10a,10b-decahydro-2H-benzo [ h] chromene-3-carboxylate monohydrate) has been determined. The tricyc lic compound has the same configuration at C3 (S), C9 (R) and C10 (S) (steriod numbering) as Veratrum alkaloids. The relative stereochemistr y is cis for the A/B ring junction, anti between C10 methyl and C9 car bolactone and cis for the B/C ring junction.