STRUCTURE OF AN OPTICALLY-ACTIVE ANTHRACYCLINE PRECURSOR

Authors
KAMEI S SAKAI Y OHASHI Y ADACHI A TANINO K KUWAJIMA I
Citation
S. Kamei et al., STRUCTURE OF AN OPTICALLY-ACTIVE ANTHRACYCLINE PRECURSOR, Acta crystallographica. Section C, Crystal structure communications, 49, 1993, pp. 1509-1511
Citations number
5
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
49
Year of publication
1993
Part
8
Pages
1509 - 1511
Database
ISI
SICI code
0108-2701(1993)49:<1509:SOAOAP>2.0.ZU;2-4
Abstract
The crystal structure of -methylthio-1,2,3,4-tetrahydronaphthalene-1,8 -diyl dibenzoate contains two independent molecules. These molecules h ave a similar conformation except for the dihedral angles between the aromatic ring and the benzoyloxy group linked to it, which differ by a relative rotation of -160-degrees. The absolute configurations of the two chiral centres C8 and C10 are established as S and S.