KINETICS OF FORMATION OF ZWITTERIONIC COMPLEXES BETWEEN 1,3,5-TRINITROBENZENE AND DIAZABICYCLO DERIVATIVES

Authors
BOGA C FORLANI L
Citation
C. Boga et L. Forlani, KINETICS OF FORMATION OF ZWITTERIONIC COMPLEXES BETWEEN 1,3,5-TRINITROBENZENE AND DIAZABICYCLO DERIVATIVES, Journal of the Chemical Society. Perkin transactions. II (Print), (10), 1998, pp. 2155-2157
Citations number
26
Categorie Soggetti
Chemistry Physical","Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Perkin transactions. II (Print) → ACNP
ISSN journal
03009580
Issue
10
Year of publication
1998
Pages
2155 - 2157
Database
ISI
SICI code
0300-9580(1998):10<2155:KOFOZC>2.0.ZU;2-T
Abstract
The title reactions are a simple model of nucleophilic attack of terti ary nitrogen on aromatic sp(2) carbons activated by the presence of ni tro groups. The formation of the zwitterionic complexes is mildly affe cted by solvent changes and by addition of tetraethylammonium chloride . The reactivity of 1,4-diazabicyclo[2.2.2]octane, quinuclidine and 1, 8-diazabicyclo[5.4.0]undec-7-ene is compared with that of primary and secondary amines.