SYNTHESIS AND STRUCTURE OF (MO3S7[S2P(OC2H5)(2)](3))) MO3S4[S2P(OC2H5)(2)](4)(SCN)) AND INTERACTION BETWEEN THEIR CLUSTER UNITS

Authors
ZHUANG HH WU DM DENG SQ ZHANG XM HUANG JQ HUANG JL
Citation
Hh. Zhuang et al., SYNTHESIS AND STRUCTURE OF (MO3S7[S2P(OC2H5)(2)](3))) MO3S4[S2P(OC2H5)(2)](4)(SCN)) AND INTERACTION BETWEEN THEIR CLUSTER UNITS, Science in China. Series B, Chemistry, life sciences & earth sciences, 41(5), 1998, pp. 510-519
Citations number
15
Categorie Soggetti
Chemistry
Journal title
Science in China. Series B, Chemistry, life sciences & earth sciences → ACNP
ISSN journal
1001652X
Volume
41
Issue
5
Year of publication
1998
Pages
510 - 519
Database
ISI
SICI code
1001-652X(1998)41:5<510:SASO(M>2.0.ZU;2-M
Abstract
The synthesis method and crystal structure of a novel Mo-3 cluster com pound are reported. The results oi structural analysis and the quantum calculation for the entire cluster molecule reveal that though two Mo -3 cluster units, which belong to two different kinds oi structural ty pe respectively, show an apparent ionic characteristic, the interactio n between them via the bridging S atoms is still quite certain. The re lationship between cluster electron counting and stability of the Mo-3 clusters are also primarily discussed.