Da. Shelkov et al., CARBON, NITROGEN, ARGON AND HELIUM STUDY OF IMPACT DIAMONDS FROM EBELIAKH ALLUVIAL DEPOSITS AND POPIGAI CRATER, Meteoritics & planetary science, 33(5), 1998, pp. 985-992
Nineteen diamond aggregate specimens (1-2 mm in size) from impactites
of Popigai crater and five diamond samples (5-7 mm in size) from Ebeli
akh river placers were studied. Our investigations indicate that sampl
es fi om Ebeliakh were formed in an impact event with the exception of
one specimen (Y7). The carbon isotopic composition of diamonds from P
opigai varies within the previously reported limits (delta(13)C, -8 to
-22 parts per thousand); whereas, diamonds from Ebeliakh placers show
heavier values of delta(13)C (-7 to -10 parts per thousand). All the
specimens studied contain very low amounts of N, mostly <20 ppm, but a
few contained up to 60 ppm. For specimens, where the quantity of N al
lowed reliable analysis, delta(15)N values were found to be in the ran
ge of -3.9 to +11.9 parts per thousand. On the basis of combined Ar an
d N study, it was concluded that impact diamonds studied here can be a
mixture of at least two types of gas carriers (e.g., different diamon
d components). A possible explanation would be involvement of a carbon
vapour deposition (CVD) process or diamond growth in the impact melt
in addition to the direct graphite-diamond shock transformation. The d
elta(13)C distributions and different N/Ar-36 correlations have indica
ted a difference between impact diamonds from Ebeliakh and diamonds ex
tracted from Popigai crater. This could be explained by the existence
of different diamond populations formed during the Popigai impact even
t. On the other hand, Ebeliakh diamonds could have resulted from a sep
arate impact event to Popigai and an alternative crater is yet to be f
ound.