CALCIUM COMPLEXES OF CARBOXYLATE-CONTAINING POLYAMIDE WITH STERICALLYDISPOSED NH-CENTER-DOT-CENTER-DOT-CENTER-DOT-O HYDROGEN-BOND - DETECTION OF THE POLYAMIDE IN CALCIUM-CARBONATE BY 13C CROSS-POLARIZATION MAGIC ANGLE SPINNING SPECTER/
N. Ueyama et al., CALCIUM COMPLEXES OF CARBOXYLATE-CONTAINING POLYAMIDE WITH STERICALLYDISPOSED NH-CENTER-DOT-CENTER-DOT-CENTER-DOT-O HYDROGEN-BOND - DETECTION OF THE POLYAMIDE IN CALCIUM-CARBONATE BY 13C CROSS-POLARIZATION MAGIC ANGLE SPINNING SPECTER/, Macromolecules, 31(21), 1998, pp. 7119-7126
Carboxylate-containing polyamides were synthesized from 2,6-di(amino)b
enzoic acid and dimethylmalonyl dichloride, isophthaloyl dichloride, a
nd fumaryl dichloride. These polymers, {NHC6H3(COO)NHCOC(CH3)(2)CO}(n)
, {NHC6H3(COO)NHCO-m-C6H4CO}(n), and {NHC6H3(COO)NHCO-trans-CH= CHCO}(
n), have seven to eight carboxylate units in a polymer chain, and thei
r Ca(II) complexes possess NH ... O hydrogen bonds, which prevents the
Ca-O dissociation by hydrolysis. CaCO3 was obtained from aqueous Ca2 and CO32- in the presence of the polyamide or the Na salt of these po
lyamides ([Ca2+]/ [monomer unit] = 100) to give calcite, vaterite, and
/or their mixture. We were able to observe polymers in CaCO3 utilizing
the C-13 cross-polarization/magic angle spinning solid-state NMR. The
binding of Ca(II) by carboxylate appears to be an important factor in
these studies and may be relevant to biomineralization of CaCO3.