INFLUENCE OF SALTING-OUT EFFECTS, TEMPERATURE AND THE CHEMICAL-STRUCTURE OF THE EXTRACTANT ON THE RATE OF COPPER(II) EXTRACTION FROM CHLORIDE MEDIA WITH DIALKYL PYRIDINE DICARBOXYLATES
C. Bouvier et al., INFLUENCE OF SALTING-OUT EFFECTS, TEMPERATURE AND THE CHEMICAL-STRUCTURE OF THE EXTRACTANT ON THE RATE OF COPPER(II) EXTRACTION FROM CHLORIDE MEDIA WITH DIALKYL PYRIDINE DICARBOXYLATES, Solvent extraction and ion exchange, 16(6), 1998, pp. 1465-1492
The kinetics of copper(II) extraction from chloride solutions with ACO
RGA CLX-50 and three model dipentyl pyridine dicarboxylates having est
er groups at various positions in the pyridine ring is investigated. I
t is shown that the extraction occurs in a diffusional regime and that
both the ionic strength and temperature have a strong effect on the r
ate of copper extraction. Basically, the initial rate of copper extrac
tion (denoted hereafter J(o)) increases as the ionic strength is incre
ased, whereas J(o) increases or decreases versus temperature depending
on the ionic strength. Such phenomena are explained in terms of salti
ng-out effects and diffusion properties. Furthermore, ACORGA CLX-50 is
shown to exhibit a good kinetic performance compared to the three mod
el dipentyl pyridine dicarboxylates.