P. Sylvester et A. Clearfield, THE REMOVAL OF STRONTIUM AND CESIUM FROM SIMULATED HANFORD GROUNDWATER USING INORGANIC-ION EXCHANGE MATERIALS, Solvent extraction and ion exchange, 16(6), 1998, pp. 1527-1539
A number of inorganic ion exchange materials that are commercially ava
ilable or under development were evaluated for the removal of strontiu
m and cesium from a simulated groundwater found in the Hanford waste s
torage area using a groundwater simulant spiked with either Sr-89 or C
s-137. The most promising materials for strontium were found to be a s
odium titanosilicate from Texas A&M University closely followed by two
titanium silicate pharmacosiderites obtained from AlliedSignal. The m
ost promising materials for the selective removal of cesium from the s
imulant was again the sodium titanosilicate followed by an alumina-pil
lared montmorillonite clay obtained from Laporte Industries Ltd. The i
on exchange kinetics were shown to be very rapid far both the titanosi
licate and the pharmacosiderite, whilst the alumina-pillared montmoril
lonite had slower kinetics more comparable to those of the zeolite AW5
00.