DIMETHYLDIOXIRANE HYDROXYLATION OF A HYPERSENSITIVE RADICAL PROBE - SUPPORTING EVIDENCE FOR AN OXENE INSERTION PATHWAY

Authors
SIMAKOV PA CHOI SY NEWCOMB M
Citation
Pa. Simakov et al., DIMETHYLDIOXIRANE HYDROXYLATION OF A HYPERSENSITIVE RADICAL PROBE - SUPPORTING EVIDENCE FOR AN OXENE INSERTION PATHWAY, Tetrahedron letters, 39(45), 1998, pp. 8187-8190
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
39
Issue
45
Year of publication
1998
Pages
8187 - 8190
Database
ISI
SICI code
0040-4039(1998)39:45<8187:DHOAHR>2.0.ZU;2-T
Abstract
Dimethyldioxirane oxidation of the hypersensitive radical probe (trans -2-phenylcyclopropyl)ethane gave non-rearranged hydroxylation products consistent with an oxene insertion mechanism for the reaction. (C) 19 98 Elsevier Science Ltd. All rights reserved.