R. Li et al., A SIMPLIFIED MODEL OF DESULFURIZATION FROM FLUE-GAS BY LOW-TEMPERATURE PLASMAS, Combustion science and technology, 136(1-6), 1998, pp. 1-12
Heterogeneous reaction is considered to be main mechanism in desulfuri
zation from the flue gas by low temperature plasmas. The radical SO3-
plays a major part in oxidizing sulfite ions to sulfate ions in refere
nce to Huie's proposal. Solving the kinetic equations reveals that the
hydroxyl radicals absorbed in the liquid phase may contribute over 85
% of desulfurization rate, which is over ten times of that due to gas
phase reactions. The predicted area factor effect is proved by the exp
eriments.