THERMAL-DEGRADATION STUDIES OF ALTERNATING COPOLYMERS - V - DEGRADATION OF THE ALTERNATING COPOLYMER OF ISOPROPENYL ACETATE AND MALEIC-ANHYDRIDE

The thermal degradation of the alternating copolymer of isopropenyl ac etate and maleic anhydride has been investigated using thermal volatil isation analysis (TVA), thermogravimetry (TG) and differential scannin g calorimetry (DSC) under vacuum and nitrogen conditions using program med heating up to 500 degrees C. The decomposition products, i.e. gas, liquid and tar fractions, have been separated and then analysed by CC -MS and FTIR spectroscopy. The structural changes in the copolymer dur ing degradation at various temperatures up to 440 degrees C and also f or isothermal heating for various periods at 170 degrees C have been i nvestigated by FTIR spectroscopy. The alternating copolymer of IPA-MAn degrades in two main stages as the temperature is progressively raise d. In the first stage up to about 260 degrees C, the acetate groups ar e completely eliminated from the isopropenyl units through side group reactions whilst leaving the backbone intact. Above 260 degrees C, the anhydride groups break down producing large quantities of CO2 and CO along with gradual breakdown of the backbone to give a variety of othe r products. Unlike the homopolymer of isopropenyl acetate, the IPA-MAn copolymer leaves a significant amount of residue after 500 degrees C. By controlled degradation at 170 degrees C, acetate groups can be rem oved without decomposition of the MAn units, to produce what is in eff ect a new copolymer of regular structure with backbone double bonds co njugated to the anhydride carbonyls. (C) 1998 Elsevier Science Limited . All rights reserved.