Av. Turik et Ag. Khasabov, ON THE DYNAMIC EFFECTIVE CHARGES OF IONS IN PEROVSKITE-TYPE ABO(3) CRYSTALS, Crystallography reports, 43(5), 1998, pp. 738-739
The dynamic effective charges are calculated for ions in ferroelectric
PbTiO3 and BaTiO3 crystals and in quantum SrTiO3 and KTaO3 ferroelect
ric crystals. It is shown that only the charges of oxygen ions can be
reliably determined from phonon spectra. The dynamic charges of ions i
n ferroelectrics are less than those in quantum ferroelectrics.