CRYSTAL AND MOLECULAR-STRUCTURES OF NICKEL(II) COMPLEX WITH ACETAMIDOBUTANONE METHYLDITHIOCARBOHYDRAZONE

Authors
NEVEROV VA BIYUSHKIN VN NEZHELSKAYA LA
Citation
Va. Neverov et al., CRYSTAL AND MOLECULAR-STRUCTURES OF NICKEL(II) COMPLEX WITH ACETAMIDOBUTANONE METHYLDITHIOCARBOHYDRAZONE, Crystallography reports, 43(5), 1998, pp. 789-792
Citations number
12
Categorie Soggetti
Crystallography
Journal title
Crystallography reports → ACNP
ISSN journal
10637745
Volume
43
Issue
5
Year of publication
1998
Pages
789 - 792
Database
ISI
SICI code
1063-7745(1998)43:5<789:CAMONC>2.0.ZU;2-L
Abstract
The structure of nickel chelate with acetamidobutanone methyldithiocar bohydrazone is determined by X-ray diffraction analysis. It is demonst rated that the nickel atom coordinates two bidentate ligands, which ar e attached to the metal atom via the sulfur atom and the nitrogen atom of the hydrazine residual. The amide nitrogen atom does not participa te in the coordination. The inference is drawn that the nickel atom ex hibits a tetrahedrally distorted planar coordination.